Elucidation of inorganic reaction mechanisms in ionic liquids: the important role of solvent donor and acceptor properties

Language
en
Document Type
Article
Issue Date
2016-10-04
Issue Year
2014
Authors
Schmeisser, Matthias
van Eldik, Rudi
Editor
Abstract

In this article, we focus on the important role of solvent donor and acceptor properties of ionic liquids in the elucidation of inorganic reaction mechanisms. For this purpose, mechanistic and structural studies on typical inorganic reactions, performed in ionic liquids, have been conducted. The presented systems range from simple complex-formation and ligand-substitution reactions to the activation of small molecules by catalytically active complexes. The data obtained for the reactions in ionic liquids are compared with those for the same reactions carried out in conventional solvents, and are discussed with respect to the donor and acceptor properties of the applied ionic liquids. The intention of this perspective is to gain more insight into the role of ILs as solvents and their interaction with metal ions and complexes in solution.

Journal Title
Dalton Transactions
Volume
43
Issue
42
Citation
Dalton Transactions 43.42 (2014): S. 15675-15692. <http://pubs.rsc.org/en/content/articlelanding/2014/dt/c4dt01239a#!divAbstract>
Zugehörige ORCIDs