[18]Annulene put into a new perspective

Language
en
Document Type
Article
Issue Date
2018-01-17
Issue Year
2016
Authors
Lungerich, Dominik
Nizovtsev, Alexey V.
Heinemann, Frank W.
Hampel, Frank
Meyer, Karsten
Majetich, George
Schleyer, Paul v. R.
Jux, Norbert
Editor
Abstract

New insights into [18]annulene were gained by looking more closely at its X-ray structure, revealing a close face-to-face stacking of 3.16 Å in a herringbone-like crystal packing. Hexadehydro[18]annulene was co-crystalized in a benzene matrix, demonstrating the stabilizing role of intercalated solvent molecules in solid annulenes.

Journal Title
Chemical Communications
Volume
52
Issue
25
Citation
Chemical Communications 52.25 (2016): S. 4710-4713. <http://pubs.rsc.org/en/content/articlelanding/2016/cc/c6cc01309k>
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