Understanding the Limitations of Charge Transporting Layers in Mixed Lead–Tin Halide Perovskite Solar Cells

Language
en
Document Type
Article
Issue Date
2022-05-19
Issue Year
2022
Authors
Zhang, Kaicheng
Forberich, Karen
Lüer, Larry
Garcia Cerrillo, José
Meng, Wei
Du, Xiaoyan
Le Corre, Vincent M.
Zhao, Yicheng
Niu, Tianq
Xue, Qifan
Editor
Publisher
John Wiley & Sons
Abstract

Lead–tin (Pb/Sn) mixed perovskites are considered as promising photovoltaic materials owing to their adjustable bandgap and excellent optoelectronic properties. The low-bandgap perovskite solar cells (PSCs) based on lead–tin mixed perovskites play a critical role in the overall performance of perovskite-based tandem devices. Nevertheless, the current record efficiencies for Pb/Sn PSCs are mostly reported in devices with p–i–n configuration rather than n–i–p, which restricts the further development of conventional perovskite-based tandem solar cells. Herein, this work systematically investigates the influence of the interlayers on the performance of low-bandgap PSCs by analyzing the energy losses in both n–i–p and p–i–n devices. Quasi-Fermi level splitting (QFLS) analysis of pristine films and films covering charge extraction layers reveals that the electron transport layer/perovskite interface is dominating the VOC losses. A joint experimental–simulative approach quantitatively determines the interface defect density to be more than one order in magnitude larger for the n–i–p architecture. Among the polymeric hole transport layers investigated for n–i–p devices, poly(3-hexylthiophen-2,5-diyl) (P3HT) exhibits the most favorable energy-level alignment to Pb/Sn perovskites. These results clarify the nature of VOC losses in Pb/Sn perovskites and highlight the necessity to develop electron extraction layers with a significantly reduced interface defect density.

Journal Title
Advanced energy & sustainability Research
Volume
3
Issue
3
Citation
Advanced energy & sustainability Research 3.3 (2022): 2100156. <https://onlinelibrary.wiley.com/doi/10.1002/aesr.202100156>
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