Few layer 2D pnictogens catalyze the alkylation of soft nucleophiles with esters

dc.contributor.authorLloret, Vicent
dc.contributor.authorRivero-Crespo, Miguel Ángel
dc.contributor.authorVidal-Moya, José Alejandro
dc.contributor.authorWild, Stefan
dc.contributor.authorDoménech-Carbó, Antonio
dc.contributor.authorHeller, Bettina S. J.
dc.contributor.authorShin, Sunghwan
dc.contributor.authorSteinrück, Hans-Peter
dc.contributor.authorMaier, Florian
dc.contributor.authorHauke, Frank
dc.contributor.authorVarela, Maria
dc.contributor.authorHirsch, Andreas
dc.contributor.authorLeyva-Pérez, Antonio
dc.contributor.authorAbellán, Gonzalo
dc.date.accessioned2022-06-22
dc.date.available2019-01-31
dc.date.created2019
dc.date.issued2022-06-22
dc.description.abstractGroup 15 elements in zero oxidation state (P, As, Sb and Bi), also called pnictogens, are rarely used in catalysis due to the difficulties associated in preparing well–structured and stable materials. Here, we report on the synthesis of highly exfoliated, few layer 2D phosphorene and antimonene in zero oxidation state, suspended in an ionic liquid, with the native atoms ready to interact with external reagents while avoiding aerobic or aqueous decomposition pathways, and on their use as efficient catalysts for the alkylation of nucleophiles with esters. The few layer pnictogen material circumvents the extremely harsh reaction conditions associated to previous superacid–catalyzed alkylations, by enabling an alternative mechanism on surface, protected from the water and air by the ionic liquid. These 2D catalysts allow the alkylation of a variety of acid–sensitive organic molecules and giving synthetic relevancy to the use of simple esters as alkylating agents.en
dc.identifier.citationNature Communications 10 (2019): 509. <https://www.nature.com/articles/s41467-018-08063-3>
dc.identifier.doihttps://doi.org/10.1038/s41467-018-08063-3
dc.identifier.eugrantERC Advanced Grant 742145 BPhosphoChem
dc.identifier.opus-id19663
dc.identifier.urihttps://open.fau.de/handle/openfau/19663
dc.identifier.urnurn:nbn:de:bvb:29-opus4-196633
dc.language.isoen
dc.publisherSpringer Nature Limited
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/deed.de
dc.subject.ddcDDC Classification::5 Naturwissenschaften und Mathematik :: 54 Chemie :: 540 Chemie und zugeordnete Wissenschaften
dc.titleFew layer 2D pnictogens catalyze the alkylation of soft nucleophiles with estersen
dc.typearticle
dcterms.publisherFriedrich-Alexander-Universität Erlangen-Nürnberg (FAU)
local.document.articlenumber509
local.journal.titleNature Communications
local.journal.volume10
local.sendToDnbfree*
local.subject.fakultaetNaturwissenschaftliche Fakultät / Department Chemie und Pharmazie
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