Singlet Fission in Carbene‐Derived Diradicaloids

dc.contributor.authorUllrich, Tobias
dc.contributor.authorPinter, Piermaria
dc.contributor.authorMesselberger, Julian
dc.contributor.authorHaines, Philipp
dc.contributor.authorKaur, Ramandeep
dc.contributor.authorHansmann, Max M.
dc.contributor.authorMunz, Dominik
dc.contributor.authorGuldi, Dirk M.
dc.date.accessioned2020-12-30
dc.date.available2023-10-11T11:35:48Z
dc.date.created2020
dc.date.issued2020-12-30
dc.description.abstractHerein, we present a new class of singlet fission (SF) materials based on diradicaloids of carbene scaffolds, namely cyclic (alkyl)(amino)carbenes (CAACs). Our modular approach allows the tuning of two key SF criteria: the steric factor and the diradical character. In turn, we modified the energy landscapes of excited states in a systematic manner to accommodate the needs for SF. We report the first example of intermolecular SF in solution by dimer self‐assembly at cryogenic temperatures.en
dc.format.extent8
dc.identifier.citationAngewandte Chemie International Edition 59.20 (2020): S. 7906-7914. <https://onlinelibrary.wiley.com/doi/10.1002/anie.202001286>
dc.identifier.doihttps://doi.org/10.1002/anie.202001286
dc.identifier.opus-id15303
dc.identifier.urihttps://open.fau.de/handle/openfau/15303
dc.identifier.urnurn:nbn:de:bvb:29-opus4-153039
dc.language.isoen
dc.publisherWiley‐VCH Verlag GmbH & Co. KGaA
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/deed.de
dc.subjectcarbenes
dc.subjectdiradicaloids
dc.subjectenergy conversion
dc.subjectself-assembly
dc.subjectsinglet fission
dc.subject.ddcDDC Classification::5 Naturwissenschaften und Mathematik :: 54 Chemie :: 540 Chemie und zugeordnete Wissenschaften
dc.titleSinglet Fission in Carbene‐Derived Diradicaloidsen
dc.typearticle
dcterms.publisherFriedrich-Alexander-Universität Erlangen-Nürnberg (FAU)
local.date.prevpublished2020-05-04
local.document.pageend7914
local.document.pagestart7906
local.journal.issue20
local.journal.titleAngewandte Chemie International Edition
local.journal.volume59
local.sendToDnbfree*
local.subject.fakultaetNaturwissenschaftliche Fakultät
local.subject.importimport
local.subject.sammlungUniversität Erlangen-Nürnberg / Eingespielte Open Access Artikel / Eingespielte Open Access Artikel 2020
Files
Original bundle
Now showing 1 - 1 of 1
Loading...
Thumbnail Image
Name:
15303_ANIE_ANIE202001286.pdf
Size:
5.97 MB
Format:
Adobe Portable Document Format
Description: