Expanding the scope of biogenic substrates for the selective production of formic acid from water-insoluble and wet waste biomass

Language
en
Document Type
Article
Issue Date
2017-07-03
Issue Year
2015
Authors
Albert, Jakob
Wasserscheid, Peter
Editor
Abstract

The selective oxidation of complex, water-insoluble and wet biomass from second and third generation to formic acid including effective catalyst recycling is reported. Additionally, the relevance and limits of potential contaminants are illustrated by different experimental approaches. By using a very robust homogeneous polyoxometalate catalyst in aqueous solution, molecular oxygen as an oxidant and an acid as a solubilizer, it is possible to convert different lignocellulosic and algae feedstock into formic acid and pure carbon dioxide. The applied green oxidation system benefits from its low reaction temperature (below 100 °C) and its very selective nature. Furthermore, catalyst recycling over three batches has been successfully carried out.

Journal Title
Green Chemistry
Volume
17
Issue
12
Citation
Green Chemistry 17.12 (2015): S. 5164-5171. <http://pubs.rsc.org/en/content/articlelanding/2015/gc/c5gc01474c#!divAbstract>
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